Please use this identifier to cite or link to this item: http://hdl.handle.net/10311/1026
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dc.contributor.authorMazimba, O.-
dc.contributor.authorMajinda, R.R.-
dc.contributor.authorMasesane, I.B.-
dc.date.accessioned2012-08-08T07:44:28Z-
dc.date.available2012-08-08T07:44:28Z-
dc.date.issued2009-
dc.identifier.citationMazimba, O. et al (2009) An unexpected 1,2-hydride shift in phosphoric acid-promoted cyclodimerization of styrene oxides under solvent-free conditions. A synthetic route towards 2,4-disubstituted 1,3-dioxolanes, Tetrahedron Letters, Vol. 50, No. 43, pp. 5927–5929en_US
dc.identifier.issn0040-4039-
dc.identifier.urihttp://hdl.handle.net/10311/1026-
dc.description.abstractA 1,2-hydride shift in the phosphoric acid-promoted cyclodimerization of styrene oxide and its chloro derivatives under solvent-free conditions leading to 2,4-disubstituted 1,3-dioxolanes is described. Methoxy substituents on the aromatic ring of the styrene oxide prevent the 1,2-hydride shift reaction leading to substituted 1,4-dioxanes. A possible mechanism for the formation of the 1,3-dioxolanes is proposed.en_US
dc.language.isoenen_US
dc.publisherElsevier Science Ltd, http://www.elsevier.com/locate/tetleten_US
dc.subject1,2-hydrideen_US
dc.subjectMethoxy substituentsen_US
dc.titleAn unexpected 1,2-hydride shift in phosphoric acid-promoted cyclodimerization of styrene oxides under solvent-free conditions. A synthetic route towards 2,4-disubstituted 1,3-dioxolanesen_US
dc.typePublished Articleen_US
dc.linkhttp://ac.els-cdn.com/S0040403909015895/1-s2.0-S0040403909015895-main.pdf?_tid=d36f06ff4a8a181084144252b430c73c&acdnat=1343892896_56b592aa5e05200086b4a429be850927en_US
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